She joins from TripleArc where she was business development director.
"Daly has a strong pedigree in print, print management and business development," said CTD chairman and chief executive Leonard Wheatley.
The move follows the firm's 2.5m investment in equipment and relocation from Twickenham, London, to Sunbury, Surrey.
Part of Daly's role will be to expand the firm's market beyond report & accounts into luxury goods.
"With that kind of work customer service and project management are critical," said Daly. "Customer service is what sets people apart, CTD has always been good, I hope to build on that.
CTD's market is familiar to Daly, who was previously sales director of St Ives Westerham Press and also worked at Astron.
Have your say in the Printweek Poll
Related stories
Latest comments
"You cannot be serious man! (J McEnroe)"
"The Daily Mail has lost its way as a newspaper."
"Very diverse of you solopress, another white male on the team. Wishing you the best of luck Greg."
Up next...
Impacted by weakening market
Acorn Press Swindon and MPD Offset cease trading
Work will move to continent
MCC to close Cwmbran site
Increasingly sophisticated systems
IFS boosts team with key hires
2.5x1.6m Nexus installed