Walker, who has 25 years of experience within the print and direct mail industry, has previously worked at Hunterprint, Waddington and Ledger, and Blackburns.
He said: "I have watched the continued growth and success of 4DM over recent years and feel privileged to have now become part of such a strong and dynamic organisation."
Group sales and marketing director Robin Skinner added: "We are delighted to have attracted this very high-calibre individual to our team.
"Martin brings huge amounts of experience and enthusiasm and will be a great asset to the 4DM business."
The appointment follows Kettering-based 4DM's recent acquisition of two new Xerox 700 digital colour presses.
4DM appoints new business development manager
Direct mail house 4DM has expanded its team following the appointment of Martin Walker as business development manager.